STANDARDS.

M A T E R I A L S A F E T Y D A T A S H E E T

SECTION 1

. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

NAME: ESSENTIAL GARLIC OIL
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS No. : 8000-78-0
FEMA No. : 2503
SYNONYMS
OIL OF GARLIC * OILS, GARLIC *

SECTION 3.

- - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

LABEL PRECAUTIONARY STATEMENTS
COMBUSTIBLE (USA)
FLAMMABLE (EU)
HARMFUL
HARMFUL IF SWALLOWED.
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
WEAR SUITABLE PROTECTIVE CLOTHING.

SECTION 4.

- - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IN CASE OF SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND
SHOES. CALL A PHYSICIAN.
IN CASE OF CONTACT WITH EYES, FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING
THE EYELIDS WITH FINGERS. CALL A PHYSICIAN.

SECTION 5.

- - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

EXTINGUISHING MEDIA
WATER SPRAY.
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
COMBUSTIBLE LIQUID.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

SECTION 6

. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR
DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
EVACUATE AREA.

SECTION 7.

- - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

REFER TO SECTION 8.

SECTION 8.

- - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED.
DO NOT BREATHE VAPOR.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
NIOSH/MSHA-APPROVED RESPIRATOR.
COMPATIBLE CHEMICAL-RESISTANT GLOVES.
CHEMICAL SAFETY GOGGLES.
KEEP TIGHTLY CLOSED.
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
STORE IN A COOL DRY PLACE.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
WASH THOROUGHLY AFTER HANDLING.
SECTION 9
. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
PHYSICAL PROPERTIES
FLASHPOINT 118F
47.77C

SECTION 10.
- - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

STABILITY
STABLE.
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE
HAZARDOUS POLYMERIZATION
WILL NOT OCCUR.

SECTION 11.

- - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

ACUTE EFFECTS
MAY CAUSE SKIN IRRITATION.
MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
MAY CAUSE EYE IRRITATION.
MAY BE HARMFUL IF INHALED.
MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
HARMFUL IF SWALLOWED.
RTECS #: LX3154800
GARLIC OIL
TOXICITY DATA
ORL-RAT LD50:1360 MG/KG TOFOD5 8,91,1985
ORL-MUS LD50:850 MG/KG TOFOD5 8,91,1985
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.

SECTION 12.

- - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

DATA NOT YET AVAILABLE.

SECTION 13.

- - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF
THIS MATERIAL.
THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL INCINERATOR
EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14.

- - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

CONTACT GOMEI FOR TRANSPORTATION INFORMATION.

SECTION 15.

- - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

EUROPEAN INFORMATION
CAUTION: SUBSTANCE NOT YET FULLY TESTED.
FLAMMABLE
HARMFUL
R 10
FLAMMABLE.
R 22
HARMFUL IF SWALLOWED.
S 16
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION
FEREAC 54,7740,1989
NOHS 1974: HZD A1267; NIS 2; TNF 246; NOS 8; TNE 4148
NOES 1983: HZD A1267; NIS 2; TNF 209; NOS 2; TNE 2255
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

SECTION 16.

- - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 2001 SIGMA-ALDRICH CO.